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By Ana Marie Cox
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Extra resources for Dog Days
P. J. Estrup and E. G. McRae, Surfucr S r i . , 1971, 25, I . In9M. B. Webb and M. G. Lagally, in ‘Solid State Physics’, ed. H. Ehrenreich, F. Seitz, and D. Turnbull, Academic Prcss, New York, 1973, Vo!. 28. 14‘’ T. N. Rhodin and S . Y. Tong, Phys. Today, 1975, October, p. 23. D. L. Adams and U . Landman, ’The Use of Direct Methods in the Analysis of LEED’, to be published in ‘Advances in Characterization of Metal and Polymer Surfaces’, ed. I,. H. Lee. ‘lL C. J. Davisson and L. H . Genner, P k y s .
Local coupling) along with parameters used in the calculations, and compare with available experimental values. 6 - -141 -I 6 5 u4 6 7 8 d l aa. u lI 9 10 I of'rare rare gases wirh Be ( h u p = 19 eV). The He resulls were Figure 7 Interaction potenrials of' obtained as described. 0306 ( a : ) for Ne, Ar, Kr,and X e , respectively. ,1976, 18, 814) IL3 ,M. Jonson and G. Srrnivasan, Phys. Letrers, 1973, A43, 427. R. S a u :tiid R. P. , 1973, 34, 268. W. D. Thesis. University of California. Bcrkcley, 1971 (unpublished).
The quantity of interest is the change in kinetic energy, AT, of the combined systcm [equation (6211, where T d and + AT[n,] = Td[nc] - T,[rr*,nM] (62) T , are the kinetic energies of the atom and metal electrons at a distance d and infinite separation, respectively. n,, nA, and IlM are the electron number densities of the combined atom-surface system, isolated atom and metal, respectively, and 11: corresponds to rin + nM. Thc change in kinetic energy, AT, in cyuation (62), is calculated 47 by combining first-order perturhation theory and the variational principle expressed in equations (55)--(57).